Journal
CHEMICAL SCIENCE
Volume 3, Issue 11, Pages 3170-3174Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc20914d
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Funding
- National Science Foundation [DGE-1144469]
- California Institute of Technology
- NIH [NIGMS RGM097582A]
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An operationally simple, copper-catalyzed arylation of N-tosyltryptamines provides direct access to C3-aryl pyrroloindolines. A range of electron-donating and electron-withdrawing substituents is tolerated on both the indole backbone and the aryl electrophile. These reactions occur under ambient temperatures and with equimolar quantities of the coupling partners.
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