Journal
CHEMICAL SCIENCE
Volume 2, Issue 9, Pages 1842-1849Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00124h
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- Deutsche Forschungsgemeinschaft
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A series of enamines undergoes anti-Markovnikov hydroboration with Piers' borane HB(C6F5)(2) to yield C-2-bridged frustrated N/B Lewis pairs, featuring weak N center dot center dot center dot B interaction. Some examples show typical frustrated Lewis pair reactions with dihydrogen or with 1-alkynes. One such N/B FLP serves as an active catalyst for the hydrogenation of enamines. Many of the new compounds were characterized by X-ray diffraction.
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