Journal
CHEMICAL SCIENCE
Volume 2, Issue 4, Pages 723-727Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00483a
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Funding
- SNF-DFG [2OPA21-126711/1]
- ETH Zurich
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A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.
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