Journal
CHEMICAL SCIENCE
Volume 2, Issue 12, Pages 2417-2422Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00478f
Keywords
-
Categories
Funding
- UPMC
- CNRS
- ANR BLANC Allenes
- Ministere de l'Enseignement Superieur et de la Recherche
- IUF
Ask authors/readers for more resources
The intermediacy of gold acetylides in the gold(I)-catalyzed cycloisomerization of enynes was questioned. While dinuclear gold complexes are observed under electrospray ionization conditions, the solution reactivity of gold acetylides also leads to the conclusion of their high affinity for the second coordination of a gold moiety, leading to dinuclear gold complexes. However, the involvement of gold acetylides and the corresponding diaurated species in the elementary steps of cycloisomerization mechanisms of enynes appears unlikely.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available