4.8 Article

A stepwise transition from microporosity to mesoporosity in metal-organic frameworks by thermal treatment

Journal

CHEMICAL SCIENCE
Volume 2, Issue 1, Pages 103-106

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00320d

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Funding

  1. U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001015]

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A Cd MOF with twisted partially augmented the net was synthesized. Activation at increasing temperatures revealed an unprecedented stepwise transition from microporosity to mesoporosity. This thermal treatment may serve as an alternative approach for the preparation of mesoporous MOFs.

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