Journal
CHEMICAL SCIENCE
Volume 2, Issue 5, Pages 858-861Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00027f
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Funding
- NSF [CHE-0924410]
- RHODIA Inc
- DFG
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It is shown that vanadium-iminato ligands are more efficient than imidazolidin-2-iminato substituents to delocalize the spin density from a phosphorus nucleus. However, the latter is stabilizing enough to allow for the isolation and characterization in the liquid and solid states of a neutral phosphinyl radical.
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