Journal
CHEMICAL SCIENCE
Volume 2, Issue 5, Pages 928-931Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00579g
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Funding
- Cluster de recherche Chimie de la Region Rhone-Alpes
- MIT foundation
- ANR [ANR08-BL34507]
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Grafting of (Me3Si)(2)N-AuPMe3 on SiO2-(700) leads to the formation of [( SiO)Au-PMe3] located in different surface environments due to the presence or absence of adjacent siloxane bridges, as shown both by P-31 solid state NMR and by its conversion into a mixture of [( SiO)Au-PMe3] and [( SiO)Au(PMe3)(2)] upon exposure to PMe3.
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