Journal
CHEMICAL SCIENCE
Volume 1, Issue 6, Pages 772-775Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00314j
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Funding
- University of Toronto
- National Science and Engineering Council of Canada (NSERC)
- Canada Foundation for Innovation
- Ontario Research Fund
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A counterion-induced polyelectrolyte collapse strategy has been developed for the preparation of poly(acrylic acid) stabilized palladium nanoparticles (NP-Pd-PAA). The structure and composition of the nanoparticles were investigated via transmission electron microscopy, dynamic light scattering, powder X-ray diffraction, and X-ray photoelectron spectroscopy. NP-Pd-PAA catalyzed fully aqueous Suzuki coupling reactions at loadings as low as 0.01 mol% Pd.
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