Journal
CHEMICAL SCIENCE
Volume 1, Issue 2, Pages 254-257Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00109k
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Funding
- National Science Foundation under the Center for Chemical Innovation in Stereoselective C-H Functionalization [CHE-0943980, CHE-0750273]
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Rhodium(II)-catalyzed reactions of donor/acceptor carbenoids can be achieved with catalyst loadings as low as 6 x 10(-7) mol equivalents when the reactions are conducted in the absence of solvent. ReactIR studies demonstrate that donor/acceptor carbenoids are ideal for achieving high catalyst turnover numbers due to the rapid reactions of their diazo precursors and the enhanced selectivity of this class of carbenoids.
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