Journal
CHEMICAL SCIENCE
Volume 1, Issue 3, Pages 383-386Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00279h
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Funding
- Syngenta
- Royal Society
- EPSRC [EP/H021620/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H021620/1] Funding Source: researchfish
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An efficient, mild and operationally simple Ni-catalysed sp(3)-carbon-to-sp(3)-carbon homocoupling of unactivated alkyl bromides has been developed and utilised in the active metal template synthesis of an alkyl chain axle [2]rotaxane. The key to the transformation is the use of tridentate nitrogen-donor-atom (terpy or pybox derived) ligands which inhibit competing beta-hydride elimination of alkyl-Ni intermediates.
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