Journal
CHEMICAL SCIENCE
Volume 1, Issue 1, Pages 68-71Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sc00198h
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- JST
- MEXT [21685007]
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A nano-sized M12L24 coordination sphere coated with 24 hexapeptide aptamers (Arg-Lys-Leu-Pro-Asp-Ala: minTBP-1) was efficiently self-assembled from 12 Pd(II) ions and 24 bent ligands with minTBP-1 at their convex. The high density of aptamers covering the 3.5 nm diameter sphere resulted in irreversible immobilization on a Ti surface, in contrast to the relatively weak, reversible binding of a single aptamer.
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