Metamaterial-based integrated plasmonic absorber/emitter for solar thermo-photovoltaic systems

We present the concept of a solar thermo-photovoltaic (STPV) collection system based on a large-area, nanoimprint-patterned film of plasmonic structures acting as an integrated solar absorber/narrow-band thermal emitter (SANTE). The SANTE film concept is based on integrating broad-band solar radiation absorption with selective narrow-band thermal IR radiation which can be efficiently coupled to a photovoltaic (PV) cell for power generation. By employing a low reflectivity refractory metal (e. g., tungsten) as a plasmonic material, we demonstrate that the absorption spectrum of the SANTE film can be designed to be broad-band in the visible range and narrow-band in the infrared range. A detailed balance calculation demonstrates that the total STPV system efficiency exceeds the Shockley-Queisser limit for emitter temperatures above T-e = 1200 K, and achieves an efficiency as high as 41% for Te = 2300 K. Emitter temperatures in this range are shown to be achievable under modest sun concentrations (less than 1000 suns) due to the thermal insulation provided by the SANTE film. An experimental demonstration of the wide-angle, frequency-selective absorptivity is presented.