4.6 Article

Electrochemical performance of alpha-MoO3-In2O3 core-shell nanorods as anode materials for lithium-ion batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 9, Pages 5083-5091

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00127g

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Funding

  1. National Natural Science Foundation of China [51102041, 11104025]
  2. Fundamental Research Funds for the Central Universities [N120205001, N140505004]
  3. Program for New Century Excellent Talents in University [NCET-13-0112]

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alpha-MoO3-In2O3 core-shell nanorods were prepared by a facile two-step hydrothermal method. As the anode of lithium-ion batteries, their reversible capacity was up to 1304 mA h g(-1) at 0.2 C rate ( 5 hours per half cycle) and maintains 1114 mA h g(-1) after 50 cycles. At a rate of 0.3 C, 0.5 C, 1 C and 2 C, the discharge capacities after 50 cycles were maintained at 938, 791, 599 and 443 mA h g(-1), respectively. The enhanced electrochemical performance can be ascribed to the synergistic effect between alpha-MoO3 and In2O3, one-dimensional core-shell nanostructures, short paths for lithium diffusion and interface spaces.

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