Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 47, Pages 23677-23683Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta06158j
Keywords
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Funding
- National Natural Science Foundation of China [51173033, 51572060, 51502062]
- Fundamental Research Funds for the Central Universities [HIT.BRETIII.201224, 201312]
- Program for Innovation Research of Science in Harbin Institute of Technology (PIRS of HIT) [201506]
- Excellent Youth Foundation of Heilongjiang Scientific Committee [JC2015010]
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FLexibLe Lithium ion batteries with high energy density have recenty received tremendous interest due to their potentiaL applications in flexible electronic devices. Herein, we report a simple high energy ball-milling technique together with vacuum filtration to fabricate a highy flexible, conductive, robust and free-standing RGO/Co9S8 nanocomposite paper with high conductivity (121 S cm(-1)), tensile strength (50.4 MPa) and Young's modulus (3.5 GPa) which can be directly used as a free-standing anode for flexible LIBs without binders, conducting agents and metallic current collectors. The free-standing RGO/Co9S8 anode with a high mass active material loading of 66.7 wt% Co9S8 can deLiver a high specific capacity of 1415 mA h gco(9)S(8) (944 mA h g(electrode),gelectrode(1)) and maintain 573 mA h gco,S-8(1) (382.2 mA h g(eletrode)-(1)) after 500 cycLes at a current density of 1C (1C = 545 mA g(-1)). More importanty, the rate capability was improved by introducing RGO. The RGO/Co9S8 anode exhibited impressive capacities of 1096.70 mA h gco,se(-1) with a capacity recuperabiLity of 69.4% as the current returned to 0.1C. These results demonstrate that the well designed nanocomposite is of great potentiaL as an anode for flexibLe LIBs. As far as we know, such improved electrochemical performance can be attributed to the nanosized Co9S8 particles with a diameter of 25 nm homogeneousLy dispersed on the surface of high conductive graphene sheets that can be obtained owing to the miLLing impact stress, which enhances surface electrochemical reactivity and shortens the transport Length of Lithium ions and electrons. What's more, the Large specific surface area of the graphene sheet enables the uniform distribution of Co9S8 and offers better ability to accommodate volume expansion/shrinkage of Co9S8 during repeated charge/discharge cycLes.
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