4.6 Article

Graphene-like carbon nanosheets prepared by a Fe-catalyzed glucose-blowing method for capacitive deionization

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 11, Pages 5934-5941

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta05713a

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Funding

  1. Science and Technology Commission of Shanghai Municipality [13NM1401200]
  2. National Basic Research Program of China [2014CB660803]
  3. Shanghai Municipal Education Commission [14ZZ097]
  4. Shanghai Special Foundation for Cultivation of Youth Teacher from Universities [B.37-0407-11-002]

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Capacitive deionization (CDI) is a new approach to produce fresh water from salted water sources. To achieve a high CDI performance, we developed a facile method for fabricating graphene-like carbon nanosheets (GCNSs) with a thickness of 2.4 nm by a Fe-catalyzed glucose-blowing approach. In this process, glucose is used as a carbon precursor, NH4Cl as a blowing agent and Fe species as a graphitization catalyst. GCNSs not only have a relatively large accessible surface area to accommodate more ions, but also have a high graphitization degree to accelerate ion diffusion. The CDI performance of GCNSs is evaluated by a batch mode electrosorptive experiment. GCNSs have higher electrosorptive capacity (38.62 mu mol L-1) compared with other carbon materials. This indicates that GCNSs are novel and potential materials for desalination.

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