Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 15, Pages 7855-7861Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00634a
Keywords
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Funding
- National Natural Science Foundation of China [51104194]
- National Key laboratory of Fundamental Science of Micro/Nano-device and System Technology (Chongqing University) [2013MS06]
- State Education Ministry
- Fundamental Research Funds for the Central Universities (Chongqing University, PR China) [CDJZR12248801, CDJZR14135501, CDJZR13130035]
- Australian Research Council [FT 110100711]
- Grain Research and Development Corporation (GRDC)
- Mount Sylvia pty. ltd.
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Herein, we demonstrate the synthesis of size- and shape-controlled MnO2 nanostructures by replica molding from diatom silica structures for high-performance supercapacitors. Three types of hierarchical hollow MnO2 patterns with different three-dimensional (3D) structures, shapes and large surface areas were successfully prepared from three diatom species by a template-assisted hydrothermal process. The extraordinary precision and nano-scale resolution of 3D replications of complex biological architecture from diatoms to artificial MnO2 structures are confirmed. Detailed electrochemical measurements reveal that the Melosira-type MnO2 pattern exhibits not only a high specific capacitance of 371.2 F g(-1) at a scan rate of 0.5 A g(-1), but also relatively good cycle stability (93.1% capacitance retention after 2000 cycles at a scan rate of 5 A g(-1)), demonstrating a promising application as supercapacitor electrode materials.
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