Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 26, Pages 13807-13818Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta02994e
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Funding
- National Natural Science Foundation of China [51472211]
- Scientific and Technical Achievement Transformation Fund of Hunan Province [2012CK1006]
- Key Project of Strategic New Industry of Hunan Province [2013GK4018]
- Natural Science Foundation of Hunan Province [2015JJ6103]
- China Scholarship Council (CSC)
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Porous hollow alpha-Fe2O3@TiO2 core-shell nanospheres for use as anode materials in lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) have been successfully fabricated by a simple template-assisted method, which has been rarely reported before. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N-2 adsorption-desorption isotherms reveal that the as-prepared alpha-Fe2O3@TiO2 is composed of a hollow inner cavity and an outer shell with massive mesopores. This porous hollow structure is capable of buffering the large volume variation of alpha-Fe2O3 during cycling and preventing the electrode from pulverization and aggregation, as well as providing sufficiently large interstitial space within the crystallographic structure to host alkalis (Li and Na). As a consequence, this hybrid composite exhibits outstanding electrochemical properties, e.g., high specific capacity, excellent cyclability, satisfactory rate performance, and splendid initial coulombic efficiency for both LIBs and SIBs.
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