4.6 Article

Hexamethylene diisocyanate as an electrolyte additive for high-energy density lithium ion batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 16, Pages 8246-8249

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta07055k

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Funding

  1. 863 project [2013AA050906]
  2. Zhejiang Key Innovation Team [2013PT16]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09010403]
  4. Hundred Talents Program of the Chinese Academy of Sciences

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Hexamethylene diisocyanate can chemically react with the onium ion produced by the oxidation of propylene carbonate and in situ generate a novel interfacial layer that is stable at high potential. With an appropriate thickness of this film, LiNi1/3Co1/3Mn1/3O2 presents significantly improved rate and cycle performances when tested between 2.5 and 4.6 V (vs. Li/Li+).

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