4.6 Article

Ag+-sensitized lanthanide luminescence in Ln(3+) post-functionalized metal-organic frameworks and Ag+ sensing

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 9, Pages 4788-4792

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta06462c

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Funding

  1. National Natural Science Foundation of China [91122003]
  2. Developing Science Funds of Tongji University
  3. Science & Technology Commission of Shanghai Municipality [14DZ2261100]

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The weak fluorescence of Ln(3+)-doped (Ln = Sm, Dy, Nd, Yb, Er) metal-organic frameworks (MOFs) was greatly enhanced by Ag+. Single-phase white-light emitters based on the resulting 4d-4f heterometallic co-doped MOFs could be realized. Furthermore, the Sm3+-doped MOF has been used for highly sensitive sensing of Ag+.

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