Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 23, Pages 12145-12148Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00998g
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Funding
- 973 Program [2013CB834704]
- Provincial Key Project of China [7131253]
- National Natural Science Foundation of China [21471018, 21404010, 21201018]
- 1000 Plan (Youth)
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A microporous MOF structure, D-his-ZIF-8, with a chiral environment was synthesized via a simple ligand in situ substitution (LIS) of 2-methyl imidazolate (mIm) with D-histidine. These chiral MOF composites show exceptional selective separation capability for racemic alanine and glutamic acid, with an ee value of 78.52% and 79.44%, respectively.
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