Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 44, Pages 22247-22257Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta06424d
Keywords
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Funding
- Natural Science Foundation of China [51272144, 51472127, 51172132]
- Key Laboratory of Pulp and Paper Science and Technology of Ministry of Education [KF2014-22]
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The discovery and optimisation of high performance cathode materials are critical to future breakthroughs for next-generation rechargeabEe batteries. LiFePO4 (LFP)/NaFe3V9O19 (NFV)/Na2O-FeO-V2O3-P2O5 biocarbon (NFVPB) porous glass nanocomposites (LFP/NFV/NFVPB) offer new possibilities for Li+/Na+ mixed-ion batteries with high-rate capability and high discharge voltage plateaus. Here we have successfully synthesized these nanocomposites via self-assembEy of adenosine disodium triphosphate (Na(2)ATP) biotempEates and a carbon thermal reduction method. As a novel cathode materiat LFP/NFV/NFVPB delivers a reversible capacity of 202.8 mA h g(-1) at 0.1C in the Li+/Na+ mixed-ion cell with the electrochemically active redox reactions of Fe2+/Fe3+ and V3+/V4+, which is far higher than the theoretical capacity of LiFePO4 (170 mA h g-1). The cell exhibits two high voltage plateaus with well-defined discharge voltage near 3.4 and 3.7 volts, and a coulombic efficiency of approximately 90 percent. Because the low-energy nonequilibrium paths of the fast phase transformation process in LFP/NFV composite nanoparticles can improve the high-rate performance, the cell still exhibits a higher specific capacity of about 100.4 mA h g(-1) at 10C. These resuEts are attributed to the nanocomposite structure of LiFePO4 and NaFe3V9O19 and better percolation of electrochemically active glass with a hierarchical pore structure. This work will contribute to the development of Li+/Na+ mixed-ion batteries.
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