Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 6, Pages 2999-3005Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta05116e
Keywords
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Funding
- EPSRC IAA Partnership Development Award [RG/75759]
- Royal Society
- Trinity Hall
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We report an easy synthetic procedure to produce large, crystalline, mechanically and chemically robust ZIF-8 monoliths without using any binders or high pressures. Gas adsorption studies show that the monolithic structures retain the characteristic porosity of ZIF-8 without any damage to the micropore system, while the bulk densities and volumetric BET areas are 3 times higher than the conventional, powder material. In addition, these structures are substantially more rigid than single crystals of the material.
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