Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 18, Pages 9411-9414Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta00321k
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A Ca-bridged siloxene (Ca-siloxene) resulting from the deintercalation of Ca from CaSi2 was synthesized via a solid state reaction with ethanol wash using TaCl5. The presence of fragmented, two-dimensional siloxene planes with Ca bridging was confirmed. The Ca-siloxene exhibited tunable optical properties, as well as stable Li storage performance by Ca bridging.
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