4.6 Article

Crystalline poly(triazine imide) based g-CN as an efficient electrocatalyst for counter electrodes of dye- sensitized solar cells using a triiodide/iodide redox electrolyte

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 48, Pages 24232-24236

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta08650g

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Funding

  1. National Science Foundation [DMR 0805148]
  2. University of California Lab Fees Research Program
  3. Institute for Collaborative Biotechnologies from the U.S. Army Research Office [W911NF-09-0001]
  4. International Fulbright Science and Technology Award
  5. MRSEC Program of the NSF [DMR 1121053]
  6. NSF

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We report utilization of graphitic carbon nitride (g-CN) as an electrocatalyst for dye-sensitized solar cells (DSSCs). Crystalline poly (triazine imide) based g-CN was synthesized via a modified ionothermal method, and deposited onto the counter electrodes along with a conductive additive and a sacrificial polymer binder. The resulting DSSCs exhibited a power conversion efficiency (7.8%) comparable to that of conventional Pt catalyst (7.9%), confirming the excellent catalytic activity of poly(triazine imide) g-CN as a nonprecious metal electrocatalyst.

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