4.6 Article

Nonflammable electrolyte for safer non-aqueous sodium batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 28, Pages 14539-14544

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta03548a

Keywords

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Funding

  1. National Natural Science Foundation of China [21203110, 21371108]
  2. 973 Project of China [2011CB935901]
  3. Independent Innovation Foundation of Shandong University (IIFSDU) [2012TB001, 2012ZD008]
  4. Shandong Provincial Natural Science Foundation for Distinguished Young Scholar
  5. China Postdoctoral Science Foundation [2013M541903]

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Sodium batteries are now considered as promising low-cost alternatives for lithium batteries. However, safety problems such as fire and explosion during abuse-testing conditions hinder the development of room temperature sodium batteries. To address these issues, here we propose a nonflammable electrolyte system for sodium batteries. By introducing a high-efficiency flame-retarding additive, the carbonate based electrolyte becomes flame inhibiting. Moreover, the additive can improve the cyclability of both the acetylene black (AB) anode and the Na0.44MnO2 cathode.

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