Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 13, Pages 6739-6741Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta07196d
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Funding
- Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center - US Department of Energy, Office of Science, Office of Basic Energy Sciences
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Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.
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