Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 65, Issue 9, Pages 1084-1088Publisher
VERLAG Z NATURFORSCH
DOI: 10.1515/znb-2010-0905
Keywords
Lead(II) Complex; Crystal Structure; Solvothermal Synthesis; Hemidirected
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Funding
- National Natural Science Foundation [20961011]
- China Postdoctoral Science Foundation [20090450183]
- Natural Science Foundation of Guangxi Province [0899023, 0991284, 2010GXNSFB013017]
- Yulin Normal University
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Two new lead(II) complexes [Pb(pcih)(bha)] (1) and [Pb(pcih)(NO3)] (2 Hpcih = 1,4-bis(3 pyrid-yl)-2,3-diazo-1,3-butadiene Hbha = 2 hydroxybenzoic acid) have been synthesized by solvothermal methods and structurally characterized The single-crystal X-ray data show that the coordination spheres of the Pb2+ ions in 1 and 2 are hemidirected with stereochemically active electron lone pairs There are some significant secondary Pb N and Pb O interactions which produce two different extended structures namely a 1D chain in 1 and a 2D layer in 2 Both 1 and 2 exhibit fluorescence properties at room temperature
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