Journal
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS
Volume 225, Issue 4, Pages 146-152Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1524/zkri.2010.1194
Keywords
High pressure; X-ray diffraction; Phase transition; Lead carbonate
Categories
Funding
- Deutsche Forschungsgemeinschaft [KN 507/5-1]
- National Science Foundation - Earth Sciences [EAR-0622171]
- Department of Energy - Geosciences [DE-FG02-94ER14466]
- U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- RF programme [02.740.11.0326]
Ask authors/readers for more resources
The high-pressure room temperature behavior of PbCO3 was investigated by angle-dispersive synchrotron powder diffraction up to 16.16(5) GPa. A phase transition to a high-pressure polymorph II of lead carbonate was observed at a pressure of approximately p(c) = 8.7 GPa. Thereby, the symmetry is reduced from orthorhombic Pmcn to monoclinic P12(1)/c1. The cell parameters at p = 8.90(5) GPa are a = 5.101(1) angstrom, b = 8.303(3) angstrom, c = 5.602(2) angstrom, beta = 89.51(4)degrees, Z = 4. The transformation is supposed to be of 2(nd) order.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
