Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 644, Issue 17, Pages 1064-1070Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201800323
Keywords
Sulfur fluorides; Rhodium; Fluorido complexes; S-F activation; Sulfur tetrafluoride
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Funding
- DFG (Deutsche Forschungsgemeinschaft)
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A general route to access the Vaska type fluorido complexes trans-[Rh(F)(CO)(PR3)(2)] [R = Et (6), Ph (7), iPr (8), Cy (9), tBu (10)] was developed by treatment of trans-[Rh(Cl)(CO)(PR3)(2)] (1-5) with Me4NF. The molecular structures of 8 and 9 were determined by X-ray crystallography. Treatment of the complex 6 with SF4 resulted in the selective formation of complex cis,trans-[Rh(F)(2)(SF3)(CO)(PEt3)(2)] (11), whereas the other fluoride complexes didn't react.
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