Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 640, Issue 10, Pages 2035-2040Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201300562
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Funding
- State Key Laboratory of Coordination Chemistry of Nanjing University
- Nanjing Forestry University
- Priority Academic Program Development of Jiangsu Higher Education Institutions, College and University Graduate Research Innovation Project of Jiangsu Province [CXLX13_517]
- University Science Research Project of Jiangsu Province [13KJB220006]
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Two copper(II) complexes, namely [Cu(HL)Cl] (1) and [Cu(HL)Br](2), where HL is the multidentate Schiffbase N-[(2-oxy-acetate)benzyl]-2-aminothanol, were synthesized and fully characterized. The Cu-II ions in 1 and 2 are pentacoordinate and the coordination arrangement is best described as distorted square-pyramidal. The degradation of methyl orange (MO) was investigated using 1 and 2 as homogeneous photo-Fenton-like catalysts. 1 and 2 exhibited similar catalytic activity at neutral pH. The results suggest that they have advantages on catalyzing efficient degradation of organic dye through photo-Fenton-like reaction.
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