Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 639, Issue 1, Pages 193-196Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201200344
Keywords
Cage-like complexes; Flexible bidentate ligand; Silver; Crystal structure
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Funding
- Research Fund for the Doctoral Program of Heilongjiang Institute of Technology [2011BJ11]
- Specialized Research Funds for Science and Technology Planning Project of Heilongjiang Province [PG09J001]
- International S&T Cooperation Projects of Heilongjiang Province [WJ09B03]
- Natural Science Foundation of Heilongjiang Province [B201108]
- Heilongjiang Institute of Technology
- University of Heilongjiang
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The cage-like complex, Ag4L4(NO3)4 (1) [L = 1, 4-bis(pyridine-2-ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single-crystal X-ray analysis. Complex 1 is reported as the first cage-like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1.
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