Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 637, Issue 3-4, Pages 369-373Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201000389
Keywords
Cerium; Schiff bases; TRENDSAL ligand; Heptadentate ligands; Crystal structure
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Funding
- Government of Sachsen-Anhalt
- Otto-von-Guericke-Universitat Magdeburg
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The recently reported cerium(IV) tripodal Schiff-base complex (TRENDSAL)CeCl (TRENDSAL =[N{CH2CH2N=CH(C(6)H(2)tBu(2)-3,5-O-2}(3)](3-)) serves as excellent starting material for novel Ce4+ coordination compounds. The first cerium(IV) azide, (TRENDSAL)CeN3 and the first cationic cerium(IV) complex, [(TRENDSAL)Ce][BPh4] are both readily accessible from (TRENDSAL)CeCl via simple salt metathesis reaction.
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