Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 635, Issue 8, Pages 1149-1152Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200900175
Keywords
Chemical bonding; Chromium; Metal-metal bonds; Multiple bonds; N ligands
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The synthesis and structure of a homobimetallic chromium complex is reported. The ligand used to stabilise the quintuply bonded metals is a sterically fine-tuned guanidinate. A chromium-chromium bond length of 1.7293(12) angstrom was observed. It is the shortest metal-metal distance reported for a stable compound yet.
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