4.1 Article

An Old Reaction with New Results: The Unexpected Formation of a Rare Earth Metal Cluster Containing Six Europium Atoms

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Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200800401

Keywords

Lanthanides; Carbonyl complexes; Cluster compounds; Fluorescence; Crystal structure

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Employing a standard protocol for the preparation of a trisbenzoylacetonato europium(III) complex with 4-bromo, benzoylacetone 2 as ligand, a new europium species was synthesized and characterized. The X-ray crystal structure analysis revealed a new europium cluster consisting of six europium-centres.

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