Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 636, Issue 6, Pages 1133-1136Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200900442
Keywords
Coordination polymers; Solvothermal reactions; Fluorescence; Zinc; Metal-organic frameworks
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Funding
- National Science Foundation of China [20871027]
- Program for New Century Excellent Talents in University [NCET-07-0169]
- Analysis and Testing Foundation of Northeast Normal University
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A metal-organic coordination polymer formulated as (H3O)(2)[Zn(BTEC)] (1), where BTEC = 1,2,4,5-benzenetetracarboxylate, was synthesized by solvothermal reaction and characterized by elemental analyses, thermal stability analysis, fluorescence and IR spectroscopy, as well as single-crystal X-ray diffraction analysis. Compound 1 is a three-dimensional network containing one-dimensional rhombic channels, the sizes of the windows are approximately 8 angstrom at the widest and 4.5 angstrom at the narrowest spacing (excluding the van der Waals radius of atoms in the framework) running along the c axis. The study of the physical properties of 1 demonstrates that it exhibits intense blue fluorescence emission in solid state at room temperature.
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