Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 634, Issue 11, Pages 1911-1914Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200800259
Keywords
metal organic framework; hydrothermal synthesis; copper; squaric acid
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Herein we report synthesis of a new brucite type copper hydroxide squarate, Cu-3(OH)(2)(C4O4)(2)center dot 4H(2)O [P2(1)/c, a = 5.6437(4) angstrom, b = 12.8357(9) angstrom, c = 9.1507(6) angstrom, beta = 95.892(1)degrees and Z = 2] by hydrothermal method, and its characterization by single crystal diffraction analysis as well as by IR spectroscopy. The rather wide spread of Cu-O bond lengths, can be primarily rationalised by the Jahn-Teller effect, and secondarily by the connectivities of the CuO6 octahedra.
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