Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 634, Issue 5, Pages 845-847Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200700580
Keywords
hydrogen storage; methane storage; crystal structure; coordination polymer; cobalt(II) salt
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[Co-2(bdC)(2)(ted)]center dot 2DMF center dot 3H(2)O (2), (DMF = N,N'-dimethylformamide, bdc = 1,4-benzenedicarboxylate dianion, ted = triethylenediamine) was prepared and characterized by IR, elemental analysis, TGA, powder X-ray analysis and single-crystal X-ray determination. At ambient temperature the material [Co-2(bdC)(2)(ted)] (1) was found to be high adsorbent or methane but poor adsorbent of hydrogen.
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