Journal
WATER RESEARCH
Volume 42, Issue 19, Pages 4869-4877Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2008.09.030
Keywords
Diatomite; Ferrihydrite; Phosphorus; Adsorption
Funding
- Natural Sciences and Engineering Research Council of Canada
- China
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A novel phosphorus adsorbent, ferrihydrite-modified diatomite was developed and characterized in this study. The ferrihydrite-modified diatomite was made through surface modification treatments including NaOH treatment and ferrihydrite deposition on raw diatomite. In the NaOH treatment, surface SiO2 of diatomite was partially dissolved in the NaOH solution. The dissolved Si contributed to form the stable 2-line ferrihydrite which deposited into the macropores and mesopores of diatomite. Blocking macropores and larger mesopores of diatomite with 0.24 g Fe/g of 2-line ferrihydrite resulted in a specific surface area of 211.1 m(2)/g for the ferrihydrite-modified diatomite, which is 8.5-fold increase than the raw diatomite (24.77 m(2)/g). The surface modification also increased the point of zero charge (pH(pzc)) values to 10 for the ferrihydrite-modified diatomite from 5.8 for the raw diatomite. Because of the increased surface area and surface charge, the maximum adsorption capacity of ferrihydrite-modified diatomite at pH 4 and pH 8.5 was increased from 10.2 mg P/g and 1.7 mg P/g of raw diatomite to 37.3 mg P/g and 13.6 mgP/g, respectively. (C) 2008 Elsevier Ltd. All rights reserved.
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