Alkylphenols in Surface Sediments of the Gulf of Gdansk (Baltic Sea)

The widespread use of alkylphenols in European industry has led to their presence in the environment and the living organisms of the Baltic Sea. The present study (2011-2012) was designed to determine the concentrations of alkylphenols, 4-nonylphenol (NP) and 4-tert-octylphenol (OP), in surface sediments of the Gulf of Gdansk, a section of the Baltic that lies in close proximity to industrial and agricultural areas and borders with an agglomeration of nearly one million inhabitants. It is also where the Vistula, the largest Polish river, ends its course. In spring, large concentrations of 4-nonylphenol and 4-tert-octylphenol were washed off into the coastal zone with meltwater. In summertime, sediments near the beach had the highest alkylphenol concentrations (NP-2.31 ng g(-1) dw, OP-13.09 ng g(-1) dw), which was related to tourism and recreational activity. In silt sediments located off the coast, the highest NP (1.46 ng g(-1) dw) and OP (6.56 ng g(-1) dw) amounts were observed in autumn. The origin of OP and NP at those test stations was linked to atmospheric transport of black carbon along with adsorbed alkylphenols.