Journal
WASTE MANAGEMENT
Volume 32, Issue 8, Pages 1575-1582Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2012.03.027
Keywords
Lithium-ion battery; Valuable metals; Oxalate; Leaching; Precipitation
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Spent lithium-ion batteries containing lots of strategic resources such as cobalt and lithium are considered as an attractive secondary resource. In this work, an environmentally compatible process based on vacuum pyrolysis, oxalate leaching and precipitation is applied to recover cobalt and lithium from spent lithium-ion batteries. Oxalate is introduced as leaching reagent meanwhile as precipitant which leaches and precipitates cobalt from LiCoO2 and CoO directly as CoC2O4 center dot 2H(2)O with 1.0 M oxalate solution at 80 degrees C and solid/liquid ratio of 50 g L-1 for 120 min. The reaction efficiency of more than 98% of LiCoO2 can be achieved and cobalt and lithium can also be separated efficiently during the hydrometallurgical process. The combined process is simple and adequate for the recovery of valuable metals from spent lithium-ion batteries. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved.
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