Solid state and sonochemical syntheses of nano lead(II) chloride and bromide coordination polymers from its nitrate analog via mechanochemical crystal to crystal transformations

Reversible crystal-to-crystal transformations of 3D lead(II) coordination polymers with the ligand 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene (4-bpdh), from nitrate analoge [Pb(4-bpdh)(NO3)(2)(H2O)](n) (1) to [Pb(4-bpdh)(NO3)(Br)](n) (2), [Pb(4-bpdh)(Br)(2)](n) (3), [Pb(4-bpdh)(NO3)(Cl)](n) (4) and [Pb(4-bpdh)(Cl)(2)](n) (5) by solid state anion-replacement processes under mechanochemical reactions, have been studied. The reversible solid state structural transformations of compounds 1-5, by anion-replacement processes under mechanochemical reaction, have been verified by PXRD measurements. Nanoparticles of compounds were synthesized by sonochemical process and characterized by scanning electron microscopy (SEM), powder X-ray diffraction, IR spectroscopy and elemental analyses. The SEM images showed that morphology change occurs during solid state anion-replacements of nanocrystals. (C) 2013 Elsevier B.V. All rights reserved.