Journal
TURKISH JOURNAL OF CHEMISTRY
Volume 38, Issue 5, Pages 880-893Publisher
Tubitak Scientific & Technological Research Council Turkey
DOI: 10.3906/kim-1402-6
Keywords
Acyl phosphonates; alkynyl organoaluminum; propargylic alcohols; tris-(phenylethynyl)aluminum; tris-(propynyl)aluminum; antimicrobial activity
Funding
- Scientific and Technological Research Council of Turkey (TUBITAK)
- Turkish Academy of Sciences (TUBA)
- Middle East Technical University (METU)
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A series of propargylic alcohols containing phosphonates was synthesized by addition reactions of tris-(propynyl) and tris-(phenylethynyl) aluminum reagents to acyl phosphonates in good yields. Aromatic moieties of the acyl phosphonates with electron-withdrawing groups generally resulted in better isolated chemical yield. Selected propargylic phosphonates were tested for antimicrobial activities. Compounds 3a and 3h showed noticeable antifungal activity, especially against molds.
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