4.5 Article

Hemoglobin-mediated synthesis of PEDOT: PSS: enhancing conductivity through biological oxidants

Journal

BIOMATERIALS SCIENCE
Volume 3, Issue 3, Pages 442-445

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4bm00338a

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Funding

  1. DARPA [N66001-11-1-4126]

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Hemoglobin- and catalase-polymerized PEDOT: PSS were characterized by X-ray photoelectron spectroscopy, visible and near-IR spectroscopy, FTIR, and ESR. Hemoglobin-polymerized PEDOT: PSS possesses bipolarons, while catalase-polymerized PEDOT: PSS is dominated by polarons. Use of heme-bound iron as an oxidant yields PEDOT: PSS with conductivity of 19.5 S cm(-1) in a single-step aqueous reaction.

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