Journal
ACS Sustainable Chemistry & Engineering
Volume 3, Issue 11, Pages 2856-2865Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.5b00788
Keywords
Dynamic vulcanization; Cocontinuous phase; Cross-link; Shape memory
Categories
Funding
- Guangxi Natural Science Foundation [2015GXNSFBA139237]
- Scientific Research Foundation of GuangXi University [XTZ140787]
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Shape memory polymers (SMPs) based on fully biobased poly(lactide) (PLA)/natural rubber (NR) thermoplastic vulcanizates (TPVs) were fabricated via peroxide-induced dynamic vulcanization. Simultaneously, in situ reactive compatibilization was achieved by PLA molecule grafting onto NR chains. Differing from the general concept of spherical rubber particles being formed after dynamic vulcanization, the cross-linked NR was found to be a netlike continuous phase in the PLA matrix. This novel structure explained the surprising shape memory property of PLA/NR TPVs well (shape fixities similar to 100%, shape recoveries >95%, and fast recovery speed <15 s at the switching temperature, similar to 60 degrees C): the cross-linked NR continuous phase offers strong resilience and the PLA phase serves as the heat-control switch. We envision that the green raw materials and excellent shape memory properties of the dynamically vulcanized PLA/NR SMPs will open up a wide range of potential applications in intelligent medical devices.
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