Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 3, Issue 6, Pages 1086-1093Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.5b00009
Keywords
Hydrogen storage; Hydrazine; MIL-101; Ni; Ir
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Funding
- National Natural Science Foundation of China [21201134]
- Natural Science Foundation of Jiangsu Province [BK20130370]
- Natural Science Foundation of Hubei Province [2013CFB288]
- Creative Research Groups of Hubei Province [2014CFA007]
- Large-scale Instrument and Equipment Sharing Foundation of Wuhan University
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Highly dispersed ultrafine NiIr nanoparticles with different compositions were successfully encapsulated into the cavities of MIL-101 and applied to catalyze the dehydrogenation of hydrazine monohydrate. The catalytic activities relied on the composition of metals, support materials, alkaline, as well as the temperature strongly. Among all the catalysts tested, Ni85Ir15@MIL-101 exhibited the highest catalytic performance in the presence of NaOH at 50 degrees C. Even at 25 degrees C, the Ni85Ir15@MIL-101 exhibited the complete dehydrogenation of hydrazine with a turnover frequency value of 24 h(-1).
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