Optical, FTIR and DC Conductivity of Soda Lime Silicate Glass Containing Cement Dust and Transition Metal Ions

Four soda lime silicate glass samples of composition (70 % SiO2+ 20 % Na2O+ 10 % CaO mol %) were prepared after adding 5 wt% cement dust to each sample mixture besides 0.1 wt% of one transition metal (TM) oxide of Fe, Co or Cu. The four samples were melted by a conventional melt-annealing technique at 1400 C-a similar to for 2.5 h. Density, UV/VIS, FTIR and DC conductivity measurements were performed for each glass. Experimental results indicate that there are only slight differences in the density values. The optical spectra reveal that the TM free sample and the sample containing iron ions have the same spectral features while the samples containing copper or cobalt exhibit distinct characteristic absorption bands due to each TM ion. FTIR spectra reveal characteristic vibrational bands due to stretching and bending modes of the silicate network. DC conductivity data show variations in the values of the studied samples according to the type of TM ions added. All the experimental results were correlated with each other in accordance with the current views on the constitution of the studied glasses.