Journal
TRANSITION METAL CHEMISTRY
Volume 36, Issue 2, Pages 179-187Publisher
SPRINGER
DOI: 10.1007/s11243-010-9451-1
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Funding
- UGC, Delhi [36-28/2008 (SR), ERIP/Er 0603574/m/01/1118]
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Three nickel(II) complexes, namely [Ni(BH)(3)](H2O)(NO3)(ClO4) 1, [Ni(BH)(2)(NO3)(2)](2) and [Ni(BH)(Tren)](ClO4)(2) 3 (BH = Benzoylhydrazine, Tren = Tris(2-aminoethyl) amine) have been synthesized and characterized by physico-chemical techniques. X-ray crystallographic analysis shows the nickel to be six-coordinated in these complexes. The complexes are efficient catalysts for the dis-mutation of superoxide in alkaline DMSO-NBT assays. The IC50 values are 74,108 and 105 mu M for 1, 2 and 3, respectively.
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