Journal
TRANSITION METAL CHEMISTRY
Volume 33, Issue 7, Pages 803-807Publisher
SPRINGER
DOI: 10.1007/s11243-008-9114-7
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Funding
- Guangzhou Municipality Science & Technology Bureau of China
- National Natural Science Foundation of China
- National Key Foundation Research Development Project (973) Item of China [2007 CB815306]
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Through a new synthetic strategy, metalloporphyrins (M = Fe(III), Mn(III) or Co(II)) were covalently immobilized on styrene-methyl acrylic acid copolymer microspheres. These copolymer-immobilized metalloporphyrins were found to be more efficient catalysts than the analogous non-supported metalloporphyrins for cyclohexane hydroxylation in metalloporphyrin-O-2-ascrobate mixtures. The catalytic activities of the immobilized catalysts follow the order Fe>Mn>Co.
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