4.7 Article

Transparent Heat-Resistant PMMA Copolymers for Packing Light-Emitting Diode Materials

Journal

POLYMERS
Volume 7, Issue 8, Pages 1379-1388

Publisher

MDPI
DOI: 10.3390/polym7081379

Keywords

poly(methyl methacrylate); optical polymers; thermal resistance; packing LED

Funding

  1. Ministry of Science and Technology, Taiwan [MOST103-2221-E-110-079-MY3, MOST102-2221-E-110-008-MY3]

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Transparent and heat-resistant poly(methyl methacrylate) copolymers were synthesized by bulk polymerizing methyl methacrylate (MMA), isobornyl methacrylate (IBMA), and methacrylamide (MAA) monomers. Copolymerization was performed using a chain transfer agent to investigate the molecular weight changes of these copolymers, which exhibited advantages including a low molecular weight distribution, excellent optical properties, high transparency, high glass transition temperature, low moisture absorption, and pellets that can be readily mass produced by using extrusion or jet injection for packing light-emitting diode materials.

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