4.7 Article

Electrochemical behaviour of Ti alloys containing Mo and Ta as β-stabilizer elements for dental application

Journal

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Volume 23, Issue 12, Pages 3829-3836

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S1003-6326(13)62936-2

Keywords

Ti12Mo; Ti60Ta; Cp-Ti; open-circuit potential; potentiodynamic polarization; electrochemical impedance spectroscopy

Funding

  1. Romanian National Authority for Scientific Research, CNCS-UEFISCDI [PN-II-ID-PCE-2011-3-0218]

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Corrosion behaviour of the studied Ti12Mo and Ti60Ta alloys with the same Mo equivalent values (12%, mass fraction) together with the currently used metallic biomaterials Cp-Ti were investigated for dental applications. The electrochemical properties of the samples were examined using electrochemical techniques: such as open-circuit potential, potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS), in two electrochemical media of artificial saliva and fluoridated artificial saliva (0.1% fluoride ions, F-) at 37 degrees C. Fluoride is commonly included in toothpastes, odontological gels and dental rinses to prevent dental caries and relieve dental sensitivity. The passive behaviour for all the titanium samples is observed for both solutions. The Ti60Ta alloy appears to possess superior corrosion resistance than the Ti12Mo and Cp-Ti in both electrochemical media.

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